Millimeter and submillimeter wave spectroscopy of the deuterated ethynyl radical

Astronomy and Astrophysics – Astronomy

Scientific paper

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Deuterium Compounds, Free Radicals, Interstellar Chemistry, Millimeter Waves, Molecular Spectroscopy, Submillimeter Waves, Fine Structure, Glow Discharges, Hyperfine Structure, Molecular Rotation, Radio Astronomy, Transition Probabilities

Scientific paper

Rotational, fine, and hyperfine structure constants are presently determined in a laboratory glow discharge for the mm and sub-mm spectrum of the deuterated ethynyl radical, and used for the accurate prediction of the frequencies of the unobserved components. Since the nuclear quadrupole coupling of the deuterium nucleus is much smaller than the magnetic hyperfine interaction, the D-quadrupole is only marginally determined.

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