The ν1 and ν3 bands of 16O3: Line positions and intensities

Details The ν1 and ν3 bands of 16O3: Line positions and intensities The ν1 and ν3 bands of 16O3: Line positions and intensities

Jul 1987

adsabs.harvard.edu/cgi-bin/nph-data_query?bibcode=1987jmosp.124..209f&link_type=abstract

Journal of Molecular Spectroscopy, Volume 124, Issue 1, p. 209-217.

Computer Science

86

Scientific paper

Using 0.005 cm-1 resolution Fourier transform spectra of samples of ozone, the ν1 and ν3 bands of 16O3 have been reanalyzed to obtain accurate line positions and an extended set of upper state rotational levels (J up to 69, Ka up to 20). Combined with the available microwave data, these upper state rotational levels were satisfactorily fitted using a Hamiltonian which takes explicitly into account the strong Coriolis interaction affecting the rotational levels of these two interacting states. In addition, 350 relative line intensities were measured from which the rotational expansions of the transition moment operators for the ν1 and ν3 states have been deduced. Finally, a complete listing of line positions, intensities, and lower state energies of the ν1 and ν3 bands of 16O3 has been generated.

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