Rapid deactivation of N(2D) by O(3p) and 630 nm emission

Details Rapid deactivation of N(2D) by O(3p) and 630 nm emission Rapid deactivation of N(2D) by O(3p) and 630 nm emission

Sep 1989

adsabs.harvard.edu/cgi-bin/nph-data_query?bibcode=1989p%26ss...37.1145b&link_type=abstract

Planetary and Space Science, Volume 37, Issue 9, p. 1145-1148.

Computer Science

7

Scientific paper

Theoretical considerations show that if the rate coefficient for N(2D) + O(3P) --> N(4S) + O is indeed 2.8 × 10-11 cm3 s-1 as measured by Jusinski et al (1988) the product oxygen atoms must be in the 1D state. This is incompatible with observational data on the forbidden red line emission. Unless the train of reasoning is flawed the N(2D) - O(3P) quenching measurement must have been vitiated by some factor which did not enter a companion N(2D) - O2(X) quenching measurement.

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