The chemistry of silicon in dense interstellar clouds

Astronomy and Astrophysics – Astrophysics

Scientific paper

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Interstellar Chemistry, Interstellar Matter, Molecular Clouds, Silicon Compounds, Vapor Phases, Chemical Reactions, Star Formation Rate, Time Dependence

Scientific paper

The gas phase chemistry of silicon in dense interstellar clouds has been investigated using a pseudo-time-dependent model. Based on new ion-molecule reaction studies as well as on improvements in the knowledge of the thermochemistry of silicon-bearing species, the model contains approximately 300 gas phase reactions involving such species. Calculated abundances are presented for a number of silicon-containing molecules including those with carbon-silicon bonds. The results for a dark cloud with T = 10 K and n(H2) = 10,000/cu cm show that unless a very large depletion for silicon in the gas phase is assumed, the predicted SiO abundance is much larger than observed in such sources.

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