Band Spectrum of CIO in Flames

Computer Science

Scientific paper

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Scientific paper

BAND systems attributed to the monoxides of bromine and iodine have been obtained by Vaidya1,2 in flames of ethyl bromide and methyl iodide. Recently, Coleman and Gaydon3 have made a further study of the BrO bands using various flames, including one of hydrogen burning in a mixture of oxygen and bromine vapour ; the occurrence of the bands in this flame supports the assignment to BrO. There does not appear to be any detailed record of the corresponding band system of ClO, although Urey and Bates4 reported the existence of a band system, which they thought to be due to ClO, when chlorine was introduced into an oxy-hydrogen flame. As part of a series of investigations on the inhibitory action of halogen compounds on flames, we have examined the spectrum of a flame of hydrogen burning in an atmosphere of oxygen mixed with a little chlorine. A system of bands has been obtained in the blue to near ultra-violet, which appear to be analogous to the known systems of BrO and IO and which may therefore be assigned to CIO. The bands do not occur readily when chlorine is introduced into a carbon monoxide - oxygen flame, but have been observed, very weakly, in the outer cone of a methyl chloride - oxygen flame.

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