The emission spectrum of yttrium monoxide - New rotational and vibrational results on the A2Pi-X2Sigma+ system

Astronomy and Astrophysics – Astrophysics

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Molecular Rotation, Stellar Spectra, Vibrational Spectra, Yttrium Oxides, Emission Spectra, Franck-Condon Principle, Molecular Energy Levels, S Stars, Spectral Bands

Scientific paper

Rotational analyses are extended to the emission spectra of several more bands in the delta upsilon = 0, -1 sequences of the A2Pi-X2Sigma+ system of yttrium monoxide excited in the discharge of a hollow cathode tube. Accurate positions for 69 band heads are presented, 12 of which, principally in the delta upsilon = -1 sequence (up to the 22-23 band), are observed for the first time. A consistent set of accurate rotational and vibrational constants is obtained for both states, up to upsilon double prime = 10 and upsilon prime = 9, from global band fittings; the upsilon-connected bands are treated simultaneously. It is noted that this corresponds to the reduction of approximately 3000 line wave numbers.

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