Vanadyl 3-nor C 30 DPEP: Indicator of depositional environment of a lacustrine sediment

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Scientific paper

Vanadyl 3-nor C 30 DPEP (Fig. 1) was first isolated as the nickel complex by Fookes (1983) and is presumably formed from chlorophyll during early diagenesis. Porphyrin analyses of the extracts from the Bucomazi Formation, Onshore Cabinda, West Africa, show that the concentration of 3-nor C 30 DPEP increases systematically relative to C 32 DPEP with depth. This systematic change is not due to maturity and has been interpreted to indicate that the pH of the depositional environment of Bucomazi Formation increased with time. Superimposed on this pH change was change in oxicity, which is indicated by the change in porphyrin ratio.

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