Spectral properties of condensed phases of disulfur monoxide, polysulfur oxide, and irradiated sulfur

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Atmospheric Chemistry, Atmospheric Composition, Molecular Spectra, Planetary Atmospheres, Spectral Reflectance, Sulfur, Sulfur Oxides, Dissociation, Spectral Bands, Thermal Decomposition, Planets, Satellites, Spectra, Condensates, Irradiation, Sulfur, X-Rays, Reflectance, Disulfur Monoxide, Polysulfur Oxide, Ultraviolet, Infrared, Color, Laboratory Studies, Experiments, Optical Properties, Oxides, Data, Vapor Pressure

Scientific paper

The spectral reflectances of S2O, as well as the polysulfur oxide (PSO) condensate dissociation products of SO2 and condensates of elemental sulfur irradiated with UV light and X-rays, have been ascertained in the 200-1700 nm range with a view to the relevance of these compounds to the interpretation of planetary data. While S2O is a dark red solid, PSO is a pale yellow one that absorbs strongly in the UV but exhibits no bands in either the visible or near IR. Elemental S produces strong bands in the UV, and while it is normally white at room temperature, UV irradiation causes it to turn yellow. X-ray irradiation of S turns it orange.

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