Fully relativistic B -spline R -matrix calculations for electron collisions with mercury

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Atomic Excitation And Ionization By Electron Impact

Scientific paper

Results from a fully relativistic 36-state Dirac B -spline R -matrix (close-coupling) calculation for e -Hg collisions are reported. Angle-integrated and angle-differential cross sections for elastic scattering and excitation of the (6s6p)P30,1,2o and (6s6p)P11o states are compared to experimental data and predictions from other theories. We generally obtain a significant improvement in the agreement between experiment and theory compared to previous distorted-wave and close-coupling attempts, in particular, for the near-threshold region that is dominated by various 6s6p2 negative-ion resonances.

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