The submillimeter wave spectrum of the protonated and deuterated carbon dioxide

Details The submillimeter wave spectrum of the protonated and deuterated carbon dioxide The submillimeter wave spectrum of the protonated and deuterated carbon dioxide

Jan 1986

adsabs.harvard.edu/cgi-bin/nph-data_query?bibcode=1986jchph..84...10b&link_type=abstract

Journal of Chemical Physics (ISSN 0021-9606), vol. 84, Jan. 1, 1986, p. 10-15. Research supported by the Etablissement Public Re

Astronomy and Astrophysics

Astrophysics

20

Carbon Dioxide, Cosmochemistry, Deuterium Compounds, Hydrogen Compounds, Molecular Ions, Vibrational Spectra, Astrophysics, Carcinotrons, Molecular Spectra, Submillimeter Waves

Scientific paper

The submillimeter wave spectrum of the protonated carbon dioxide has been investigated in the 340-406 GHz frequency range by using a phase locked submillimeter carcinotron. A magnetically confined glow discharge in a mixture of CO2, H2/D2, and Ar has been used to produce the molecular ions. The rotational lines investigated are characterized by J = 15-18, K-alpha not greater than 5 for HCO2(+) and J = 16-19, K-alpha not greater than 6 for DCO2(+). From the analysis of the spectra, accurate molecular constants have been derived, leading to the prediction of transitions of astrophysical interest.

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