Photochemistry and molecular ions in carbon-rich circumstellar envelopes

Astronomy and Astrophysics – Astrophysics

Scientific paper

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Carbon, Interstellar Chemistry, Molecular Ions, Photochemical Reactions, Stellar Envelopes, Abundance, Cool Stars, Hydrocyanic Acid, Reaction Kinetics, Spatial Distribution, Stellar Models

Scientific paper

The authors' earlier theory of ionization of C-rich circumstellar envelopes based on the photochemical model is extended to include the temperature dependence of ion-molecule reactions with polar molecules, particularly HCN, and line self-shielding of CO dissociating radiation. The results are applied to the abundances of HCO+ and HNC in C-rich circumstellar envelopes. With standard parameters for IRC +10216, the model is found to be consistent with the new upper limit to the antenna temperature of the J = 1-0 line of HCO+ obtained with the IRAM 30-m telescope. The photochemical model provides a natural explanation of the relatively large ratio of HCN to HNC observed for C-rich circumstellar envelopes, and good agreement is obtained for the H13CN/HNC antenna temperature ratio measured for IRC +10216.

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