Hydrogen isotope fractionation between ice and water

Computer Science

Scientific paper

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Scientific paper

The equilibrium constant for the exchange of deuterium between ice and water is calculated from available thermodynamic data. At 0°C. ice is enriched in deuterium by 1.92 per cent compared to the water with which it is in equilibrium. The effect of dissolved salts is estimated to be only a lowering of the freezing-point. The application to some natural processes is considered.

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