Grating anomalies in porphyrin spectra

Details Grating anomalies in porphyrin spectra Grating anomalies in porphyrin spectra

Jul 1971

adsabs.harvard.edu/cgi-bin/nph-data_query?bibcode=1971gecoa..35..743r&link_type=abstract

Geochimica et Cosmochimica Acta, vol. 35, Issue 7, pp.743-747

Mathematics

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Scientific paper

Experimental evidence is presented to show that porphyrin spectra are modified by grating anomalies to such an extent that interpretation is difficult. The anomalies appear in a definite wavelength region which depends on the optical properties of individual grating monochromators, and are associated with polarization effects. The presence of light-scattering material in the samples of any fluorescent compounds may induce the formation of grating anomalies in their fluorescence spectra. The anomalies may easily be mistaken for porphyrin peaks, especially in samples which contain light-scattering material such as those from geological sources.

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