Peculiarities of the Bound Water and Water Ice Seasonal Variations in the Martian Surface Layer of the Regolith.

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Introduction: The processes of the hydration/ dehydration of salt minerals within the Martian soil and the condensation/sublimation of water ice (and frost) in the surficial soil layer and on the polar cap surface play great significance in the modern water cycle on Mars and directly affect the redistribution of the water phases and forms in the system "atmosphere/regolith/polar caps" [1, 2, 3, 4, 5]. The processes are reversible in time and their intensity is strongly dependent on such time-variable climatic parameters as atmospheric and surface temperature, atmospheric water vapour content and specific features of atmospheric seasonal circulation [6, 7, 8, 9, 10]. In the work we report the study results of the seasonal variations of the chemically bound water (BW) spectral signature (based on the TES and OMEGA data), estimation and mapping of the winterand spring-time water ice increase within the Martian surface soil (based on the TES and HEND data). Analysis and results: Regional and global mapping of the BW spectral index distribution as function of the seasons was conducted by using of the 6.1 μm emission pick from the TES dataset and the 1.91 μm absorption band from reflectance spectra of the OMEGA data. The study of the seasonal redistribution of the water ice (and frost) within the thin surficial soil layer was conducted based on the TES thermal inertia (TI) data and the HEND neutrons flux mapping data. Bound water mapping: The mapping of the TES 6.1 μm BW index distributions was conducted at the time steps from 30° to 60° of Ls [11]. The mapping results show remarkable changes of the BW index values from one season to other one at notable latitudinal dependence of the index (Fig.1). At that, the higher BW index values are disposed mostly within the peripheral zone near the edge of the perennial and seasonal polar caps (cooler, wetter areas), while the lower BW index values are observed at low latitudes (warmer, drier areas). Between the Nspring (Ls=0°-90°) and winter (Ls=270°-360°) the zone with maximum values of BW index is shifting gradually from high latitudes to middle latitudes (20°- 30°N), being mostly disappearing in the period of Ls=150°-210°. Mapping results demonstrates that intensity of the TES 6.1 μm BW index correlates well with albedo, being higher in the brighter dusty areas and lower in the darker areas on Mars. Nevertheless, the seasonal variations of the BW index are characteristic for both bright and dark surfaces. The distinct hemispherical asymmetry of the BW index distribution is observed during the N-summer, while during the S-summer the asymmetry is much less visible. The observing time range from hydrated to dehydrated states of surface materials corresponds to the Ls range from 15° to 30° (from ~1 to 2 months). The time scale may to be conforming to the rate of the hydration/dehydration process for the Mg- and Fesulfates, composing part of the Martian soil [12, 13]. The BW index based on 1.91μm band has been mapped for spring and summer by using the OMEGA data of the first and second Martian year observations. As well in the case of the TES BW index, the mapping results of the 1.91 μm BW index also shown remarkable difference in the bound water distribution between spring and summer seasons (Fig.2). Seasonal water ice increase in the surface regolith: To define the order of the winter-time increase of the water ice within the Martian surface layer corresponding to the daily thermal skin depth (3- 10 cm in thickness) we compared the difference between the TI values mapped separately for the Nsummer- (Ls=120°-150°) and the N-winter (Ls=300°- 310°) in the latitude range ±50° out of the seasonal CO2 ice cover. We consider the summer-time and the winter-time TI values as characteristic of the dry and icy soils correspondingly. To estimate the possible water ice amount increase in the soil during winter we definition based on relationship between TI dry soil_ and TI icy soil (computed for different soil's ice content from 0% to 10%)._Following to the estimations, the zonally averaged (in 5°-latitude belts) winter-time TI values are consistent with a soil's ice content from 2-8 vol. % in the latitude ranges 30°-50°N and 40°-50°S to < 1 vol. % (and up to dry soil) at a lower latitudes 0-30° S/N. The water ice volume part was estimated for all coincided summer and winter TES TI surface footprints by solving of the quadratic equation, received at inclusion of the thermal parameters for two-component mixture (soil+ice) into formula of thermal inertia [15]. The estimated winter-time amount of water ice in the Martian soil was globally mapped and the received result is shown on Figure 3. The described method we also applied for estimation and mapping of the water ice within surficial soil in the peripheral zone of the retreating seasonal CO2 ice cap, where the polar water ice annulus (~5° circular belt) has been observed recently [16,17]. In our report we will discuss the character of the soil's water ice amount dynamics in the belt as function of the Ls and latitude. Example of the water ice amount mapping within the surficial soil in the circular belt for Ls=0-40° is shown on figure 4. As one can see from the map, the ice amount in the soil layer (with thickness 3-10cm) within the belt is varies from 3 to 11 vol. %. The seasonal variations of the water amount within thicker surface layer (up to depth 20-30 cm), we had analyzed [18] based on the HEND fast neutrons flux data (with energy range 2.5-10 Mev (FN2)) collected during two Martian years [19]. We found that distribution of the water equivalent on Mars shows notable annual differences (Fig.5). At that, the picture of the winter-time (in both hemispheres) water equivalent distribution has visible similarity with trend of the winter-time distribution of the water ice (frost) derived from the TES TI data. Conclusion: The received results of the joint analysis of the TES, HEND and OMEGA data demonstrates existence of the strong seasonal effect of the bound water and water ice amount variations in the surficial soil layer with thickness from a hundreds microns up to 20-30 cm. Appearance of the water ice in the surficial soil layer around of receding CO2 ice cap serves as direct conformation of the seasonal permafrost layer formation on Mars. Our results shown that mapped amount of the soil's water ice (involved in the seasonal redistribution) exceed notably the content of the atmospheric water. This means that the role of the regolith in the modern water cycle on Mars may to be much significant than it was suggested before. References: [1] Fanale F.P. et al., (1986), Icarus, 68, 1- 18 ; [2] Zent A.P. et al, (1995), JGR, 100, 5341-5349 ; [3] Zolotov M. Yu. (1989), LPSC XX, 1257-1258 ; [4] Mohlmann D.T.F. (2004), Icarus, 168, 318-323 ; [5] Tokano T. (2003), Icarus, 164, 50-78 ; [6] Mellon M.T. and Jakosky B.M. (1995), JGR, 100, 11781-11799 ; [7] Bottger H.M. et al., (2004), JGL, 31,L22702; [8] Smith M.D. (2004), Icarus, 167, 148-165 ; [9] Bish D.L. et al., (2003), Icarus, 164, 96- 103 ; [10] Kuzmin R.O. et al., (2007), Solar System Reseach, 41, 99-102 ; [11] Kuzmin R.O. et al., (2006), LPSC XXXVII, #1846 ; [12] Chipera S.J., Vaniman D.T. (2007), Geoch. et Cosmoch. Acta, 71, 241-250 ; [13] Chou I-M, R.R. Seal II (2007), JGR, 112, E11004, doi : 10.1029/2007JE002898 ; [14] Kuzmin R.O. et al., (2007) 7th Mars Conf., #3022; [15] Kuzmin R.O. et al., (2007), Europian Mars Science and Exploration Conference : Mars Express & ExoMars, # 1120023 ;[16] Titus, T.N. (2005), Lunar. Planet. Sci.XXXVI, Abstract #1993; [17] Wagstaff, K.L., T.N. Titus, A.B. Ivanov, R. Castano, J.L.Bandfield. (2008), Planetary and Space Science, 56, 256-265;[18] Kuzmin R.O. et al., (2007), Brown-Vernadsky Microsymp. 46th (www.planetology.ru/micro.php.); [19] Litvak M.L. et al., (2007), Solar System Reseach, 41,5, 385-397. used the nomogram [14], created for ice content

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