The Mg-Cr relationship in achondrites and in the silicate fraction of mesosiderites, and additional observations on eucrites

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Achondrites, Chromium, Magnesium, Silicates, X Ray Fluorescence, Chemical Composition, Classifications, Computerized Simulation, Correlation, Crystallization, Least Squares Method, Tables (Data)

Scientific paper

New data are used to confirm the positive correlation between Mg and Cr in howardites and eucrites, and the identity of the Mg/Cr ratio in the two meteorite groups is established, provided Chaves is treated as an anomalous howardite. Macibini, usually classed as a eucrite, has higher contents of Mg and Cr than all but the cumulate eucrites; the suggestion is made, on the basis of its polymict character, the wide compositional range of its constituent clasts, and its bulk chemistry, that it should be re-classified as a howardite.
The Mg-Cr relationship in diogenites is one of almost constant Mg but extremely variable Cr. The "average diogenite" plots fairly close to the trend established for the howardites and eucrites, indicative of the genetic link between these three meteorite classes.
The silicate fractions of nine mesosiderites studied do not show a close coherence of Mg and Cr. With the exception of Patwar, they contain more Cr than howardites and eucrites, and exhibit greater variation of Cr relative to Mg. The general lack of clear inter-element trends in these silicate fractions suggests that they had a more complex origin and evolution than the silicates of the achondrites.
Preliminary results of quantitative computer modeling of major and trace elements in the eucrites indicate that about 32 percent fractional crystallization of a eucritic liquid of the composition of Sioux County yields a residual liquid similar to Nuevo Laredo; the cumulate produced has the approximate composition of the cumulate eucrite Moama. These results are in agreement with the model developed by Consolmagno and Drake (1977), using the rare earth elements, for a corresponding stage in the solidification of an initial eucritic liquid produced by equilibrium partial melting of the source region of the parent body (Stolper, 1977). Plotting of the Ti concentrations of the meteorites studied against their Fe/Fe+Mg ratios supports Stolper's idea that the eucrites and the Mg-rich achondrites do not lie on the same liquid line of descent, and shows that the mesosiderite silicates do not conform to either trend.

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