Interstellar polyynes from the disruption of carbon grains

Astronomy and Astrophysics – Astronomy

Scientific paper

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Carbon, Interstellar Chemistry, Polyatomic Molecules, Molecular Clouds, Molecular Interactions, Photodissociation, Shock Waves

Scientific paper

Carbon grains disrupted by shocks in diffuse interstellar clouds release substantial abundances of large carbon-chain molecules into the gas, where they are destroyed by photodissociation and gas-phase reaction. The column density arising from a single shock for molecules containing ≡10 atoms is calculated to be ≡1011cm-2. This is a value unlikely to be obtained by gas-phase reactions in diffuse clouds. The chemistry of the large carbon-chain molecules should reflect the conditions appropriate to the cool atmospheres of carbon-rich stars, rather than the situation in an interstellar cloud.

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