Adsorption of non-ionic aliphatic molecules from aqueous solutions on montmorillonite. Clay-organic studies--II

Details Adsorption of non-ionic aliphatic molecules from aqueous solutions on montmorillonite. Clay-organic studies--II Adsorption of non-ionic aliphatic molecules from aqueous solutions on montmorillonite. Clay-organic studies--II

Sep 1960

adsabs.harvard.edu/cgi-bin/nph-data_query?bibcode=1960gecoa..20...15h&link_type=abstract

Geochimica et Cosmochimica Acta, vol. 20, Issue 1, pp.15-29

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Scientific paper

A series of nonionic aliphatic compounds was adsorbed from aqueous solutions on Ca-mont-morillonite and the adsorption isotherms were determined. The differences in molar adsorption are attributed to the influence of the chain length and the CH-activity. These effects are shown to operate independently. The (001) spacings of the clay-organic complexes were measured and one-, two- and three-layer complexes were recorded. The orientation of the molecules in the one-layer complexes is discussed. It is considered that aliphatic molecules orient with the plane of their chain both parallel and perpendicular to the clay surface.

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