Novel high-pressure structures of MgCO3, CaCO3 and CO2 and their role in Earth's lower mantle

Details Novel high-pressure structures of MgCO3, CaCO3 and CO2 and their role in Earth's lower mantle Novel high-pressure structures of MgCO3, CaCO3 and CO2 and their role in Earth's lower mantle

Aug 2008

adsabs.harvard.edu/cgi-bin/nph-data_query?bibcode=2008e%26psl.273...38o&link_type=abstract

Earth and Planetary Science Letters, Volume 273, Issue 1-2, p. 38-47.

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Most of the oxidized carbon in the Earth's lower mantle is believed to be stored in the high-pressure forms of MgCO3 and/or CaCO3 or possibly even CO2. Recently, through ab initio evolutionary simulations and high-pressure experiments, a complete picture of phase transformations of CaCO3 at mantle pressures was obtained. Here, using the same approach, we investigate the high-pressure structures of MgCO3. Two new structure types were predicted to be stable in the relevant pressure range: one at 82 138 GPa and the other above 138 GPa. Both phases contain rings of corner-sharing CO4-tetrahedra. These predictions were largely confirmed by the experiments presented here. A number of structurally very different, but energetically competitive metastable polymorphs were found and reveal complex high-pressure chemistry of MgCO3, in contrast to CaCO3. For CO2, from 19 GPa to at least 150 GPa, we find β-cristobalite structure to be stable. Differences between high-pressure tetrahedral carbonates and low-pressure silicates are discussed in terms of rigidity of the T O T angles (flexible when T = Si and stiff when T = C). We show that through most of the P T conditions of the mantle, MgCO3 is the major host of oxidized carbon in the Earth. We discuss the possibility of CO2 release at the very bottom of the mantle, which could enhance partial melting of rocks and explain the geodynamical differences between the Earth and Venus.

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