EPR Investigation of Gamma-Irradiated Rapana Thomasiana (Gastropoda, Muricidae) Shell

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Epr And Nmr Spectroscopy, Ionizing Radiations

Scientific paper

The shell of Rapana Thomasiana snail, a carnivorous gastropod collected from the coasts of the Black Sea (Romania) was investigated by using Electron Paramagnetic Resonance (EPR) spectroscopy. The samples in powder form were irradiated with a 60Co gamma-ray source at ambient temperature in the dose range between 1.06 and 11.3 kGy. The measurements showed that the EPR signal intensity enhanced following saturation exponential with the absorbed dose. The estimated EPR parameters: g1 = 1.9976, g2 = 2.0006, g3 = 2.0015, g4 = 2.0030 and g5 = 2.0043 revealed a complex spectrum consisting of CO2-, CO33- and CO3- species. A very weak signal at g6 = 2.0057 was associated to SO2- electron center. All EPR signals of gamma-irradiated samples decreased with various rate with the of 100° C isothermal annealing time.

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