Diatom-diatom interactions with light: Applications and line shape theoretical aspects

Statistics – Applications

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Interatomic And Intermolecular Potentials And Forces, Potential Energy Surfaces For Collisions, Line Shapes, Widths, And Shifts, Scattering Of Acoustic Waves

Scientific paper

Recent advances in calculations of collision-induced absorption- and Raman-spectra in pure diatomic gases are presented. An extensive calculation of H2-H2 absorption from 40 K to 400 K has provided improved understanding of the atmosphere of Uranus. A highly advanced close-coupling calculation of H2-H2 light scattering has verified that the line shapes are affected by interference between the permanent H2 and the H2-H2 interaction-induced polarizabilities. A few directions that the research in astrophysical applications of collision-induced absorption is taking are also described. For instance, H2-H2 dipole and potential surfaces for vibrations higher than v = 1 are currently being developed to enable simulations of collision-induced absorption at temperatures relevant for white dwarf atmospheres. For low temperature N2-N2 absorption there is unresolved discrepancy between measurement and simulation. A possible solution to this puzzle is suggested.

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