Theoretical studies of interstellar processes

Astronomy and Astrophysics – Astronomy

Scientific paper

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Abundance, Curves (Geometry), Helium Hydrogen Atmospheres, Helium Ions, Hydrogen Ions, Interstellar Gas, Planetary Nebulae, Potential Energy, Recombination Coefficient, Recombination Reactions, Supernovae, Astronomical Models, Born-Oppenheimer Approximation, Cross Sections, Electron Capture, Gas Dissociation, Interstellar Chemistry, Mathematical Models

Scientific paper

We have been studying the dissociative recombination (DR) of HeH(+) with an electron with the goal of calculating accurate cross sections and rate coefficients to allow for the accurate modelling of the abundance of HeH(+) in planetary nebulae and supernova envelopes. A unique feature of the HeH potential curves is that none of the neutral states cross the ion curve. This required a new approach to the calculation of DR cross sections and rate coefficients that had not yet appeared in the literature. Because of the lack of a potential curve crossing, the initial electron capture occurs by Born-Oppenheimer breakdown, i.e. by the interaction of the motion of the incoming electron with the nuclear motion. This same mechanism also drives DR in H3(+) and the methods developed and described below for HeH(+) DR will be used for the future calculation of H3(+) DR.

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