Sr and Pb isotopes, U and Th chemistry of the alkaline Monteregian and White Mountain igneous provinces, eastern North America

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The Monteregian Hills and younger White Mountain alkaline intrusions were emplaced into the Cambro-Ordovician sediments of the St. Lawrence Lowlands and the folded and thrusted Lower Paleozoic sequence of the Appalachian orogen. Age relations indicate that there is a fine-scale structure to the igneous activity, with slightly undersaturated to critically saturated rocks emplaced between 141 and 128 Ma and strongly undersaturated rocks emplaced between 121 and 117 Ma. Sr and Pb isotopic data for the mantle-derived alkali picrite, alkali olivine basalt and basanite magmas, indicate derivation from a depleted mantle similar to that which produces present-day oceanic island basalts. For the most isotopically primitive samples, decay-corrected 87 Sr / 86 Sr = 0.7030-0.7037, 206 Pb / 204 Pb = 19.05-19.72, 207 Pb / 204 Pb = 15.56-15.65, and 208 Pb / 204 Pb = 38.64-39.26. On Pb-Sr isotope correlation diagrams the data define trends similar to those for MOR basalts, implying mantle heterogeneity which requires the presence of a component enriched in radiogenic Pb relative to Sr. The interaction of these isotopically primitive magmas with the crust can be defined in terms of a three component system: depleted mantle-Grenville age crust-Lower Paleozoic age crust. The granitic magmas were apparently derived from the Lower Paleozoic crust of the Appalachian orogen. For the mantle-derived magmas, Th/U ratios vary from 2.5 (estimated ratio for MORB source) to 5.1, with the mean value near that of the bulk earth. The variations in Th/U suggest mantle heterogeneity on a local scale, and the high Th/U of some samples suggests that the mantle was enriched in incompatible elements shortly before melting. The magmas derived by partial melting of the crust have Th/U of 3.3 to 8.7, and the higher ratios are associated with rocks crystallized from magmas that originated by melting of Lower Paleozoic sediments. The Sr and Pb isotopic data support the conclusion of et al. (1982) that the subcontinental mantle under eastern Canada underwent a Precambrian depletion event. This depleted mantle apparently extends under the White Mountain province and is isotopically similar to the mantle which gives rise to oceanic island basalts. In contrast, Pb isotopic ratios for the New England Seamount chain (TARAS and HART, 1983), which apparently represents the oceanic extension of this magmatic activity, are significantly more radiogenic. It is possible that a mantle plume provided the heat energy, and perhaps metasomatic fluids, to trigger melting in the subcontinental mantle, whereas in the case of the oceanic extension the plume directly contributed to the observed magmatism, as reflected in the more radiogenic Pb ratios.

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