Rate of CH3(+) + H2 yields CH5(+) + HV and role of electronic transitions in other radiative association processes

Astronomy and Astrophysics – Astrophysics

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Cosmochemistry, Electron Transitions, Interstellar Matter, Methane, Molecular Clouds, Reaction Kinetics, Cyclotron Radiation, Radiative Transfer

Scientific paper

A result obtained from a recent reinterpretation of experimental data on CH3++H2 → CH5++hν is used to revise values given earlier for the rate coefficients of this process at 13, 30, and 80K. It is also argued that radiative electronic transitions are responsible for stabilization in many of the ion-molecule association processes of interest in connection with interstellar cloud chemistry.

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