Trace Element Partitioning in Porphyritic, Pyroxene-rich Chondrules in Semarkona

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Chondrites: Ordinary, Chondrules, Pyroxene, Trace Elements

Scientific paper

The behavior of trace elements during chondrule crystallization has not been investigated extensively. The most detailed study is that of Alexander, who determined trace element data for olivine, pyroxene and glass for chondrules from three ordinary chondrites, Semarkona, Bishunpur and Chainpur. We have measured trace element concentrations (REE, Sr, Y and Zr) of pyroxenes and mesostases in four chondrules from Semarkona, with a view to understanding the behavior of these elements during chondrule crystallization. REE elements are incompatible in all pyroxenes, but are more strongly partitioned into Ca-rich pyroxenes than low-Ca pyroxenes. Pyroxenes have negative Eu anomalies, consistent with igneous crystallization, and mesostases have complementary positive Eu anomalies, consistent with closed system fractional crystallization of individual chondrules. Partition coefficients of many of the minor and trace elements measured are higher than equilibrium values in comparable systems. This is attributed to the rapid cooling rate of the chondrules. One of the chondrules studied has notably high REE partition coefficients for augite, close to 1. This may be attributable to the high Al2O3 content of this augite which enhances charge-balanced substitutions for M3+ cations such as REE.

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