Infrared Spectra of ACETYLENE-D2 Clusters

Details Infrared Spectra of ACETYLENE-D2 Clusters Infrared Spectra of ACETYLENE-D2 Clusters

Jun 2010

adsabs.harvard.edu/cgi-bin/nph-data_query?bibcode=2010mss..conferi06m&link_type=abstract

"International Symposium On Molecular Spectroscopy, 65th Meeting, Held 21-25 June, 2010 at Ohio State University. http://molspec

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Infrared/Raman (Vibrational)

Scientific paper

In an effort to observe the spectra of acetylene clusters (C2H2)% n with ngeq 4 and the very weakly bound He-C2H2 complex, spectra of acetylene-d2 clusters in the region of the C2D2 % ν 3 fundamental (˜ 2439 cm-1) were recorded using a tunable diode laser to probe a pulsed supersonic slit jet expansion. So far, several bands below 2439 cm-1 have been recorded. Two can be attributed to a parallel ν 3|| and perpendicular ν 3perp band for the T-shaped C2D2 dimer. The interconvesion splittings are clearly seen in these bands. There are other mystery bands whose origins are being investigated both experimentally and theoretically. In this talk I will discuss possible assignments of these bands to C2D2 clusters.

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