Radiative relaxation of molecular vibration of the nitric oxide molecule as a possible source of the infrared shuttle glow

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A model calculation to predict infrared Shuttle flow due to the radiative relaxation of vibration of the NO molecule is presented. Space Shuttles hit atmospheric NO molecules at a very high speed (~ 8 km s-1) and excite vibrational and rotational motions up to the temperature of 54,000 K. With the electric dipole radiation of Δν = 1, 2, 3, and particularly 4 (ν is the vibrational quantum number), the excited NO molecules emit infrared radiation before they collide with other molecules. The total radiation power is estimated to be 170A μW, where A is the cross-section area of the Shuttle in m2 if no adsorption of the NO molecule takes place on the Shuttle surface. The intensity of each infrared line is calculated as a function of time, including all vibrational states up to ν = 35. For example, the 5039 cm-1 line (ν = 24 --> 20) has a maximum intensity of about 2.3 × 10-21 W molecule at around 0.2 ms, which corresponds to 80 cm from the Shuttle surface if the recoil speed of the molecules is 4 km s-1.

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