The Formaldehyde Ortho/Para Ratio as a Probe of Dark Cloud Chemistry and Evolution

Astronomy and Astrophysics – Astronomy

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Ism: Abundances, Ism: Clouds, Ism: Molecules

Scientific paper

We present measurements of the H_2CO ortho-para ratio toward four star-forming cores, L723, L1228, L1527, and L43, and one quiescent core, L1498. Combining these data with earlier results by Minh et al., three quiescent cores are found to have ortho-para ratios near 3, the ratio of statistical weights expected for gas-phase formation processes. In contrast, ortho-para ratios are 1.5-2.1 in five star-forming cores, suggesting thermalization at a kinetic temperature of 10 K. We attribute modification of the ortho-para ratio in the latter cores to formation and-or equilibration of H_2CO on grains with subsequent release back into the gas phase due to the increased energy inputs from the forming star and outflow. We see accompanying enhancements in the H_2CO abundance relative to H_2 to support this idea. The results suggest that the formaldehyde ortho-para ratio can differentiate between quiescent cores and those in which low-mass star formation has occurred.

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