Sulphur isotope effects in the high temperature oxidation of troilite

Details Sulphur isotope effects in the high temperature oxidation of troilite Sulphur isotope effects in the high temperature oxidation of troilite

Nov 1983

adsabs.harvard.edu/cgi-bin/nph-data_query?bibcode=1983gecoa..47.2059m&link_type=abstract

Geochimica et Cosmochimica Acta, vol. 47, Issue 11, pp.2059-2061

Computer Science

Scientific paper

Troilite oxidation in air at 1200°C gives sulphur dioxide which is slightly enriched (~0.3%.) in 34 S. No systematic variations were seen of the isotopic compositions of product sulphur dioxide or residual troilite with extent of conversion. We speculate that the oxidation reaction takes place at the surface of the molten troilite in such a way as to inhibit mixing between the reacting outer layers and the unreacted liquid substrate so that Rayleigh behaviour with extent of reaction is not observed.

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