Potential chemical evolution of aerosols on Titan's surface: some new results on Titan's tholins

Mathematics – Logic

Scientific paper

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Scientific paper

Titan's environment hosts a complex organic chemistry that can be investigated from Earth-based laboratory experiments. One of the key astrobiological questions of Titan's environment is the fate of the organic aerosols produced in the atmosphere, after they are deposited on the surface. In the present study, we report the geological structures these aerosols may encounter in the light of the last observations of the Cassini-Huygens mission. We chose to quantify the production of some astrobiologically interesting molecules in putative ammonia-water bodies likely to be present at the surface or subsurface of Titan, as crater melt pools or cryolavas. After aerosol analogues (tholins) synthesis and surface hydrolysis simulation, some resulting products were identified and quantified. Tholins were found to be very reactive toward an oxygen source. Urea was identified as the main product of Titan's tholins hydrolysis in ammonia-water solutions, with a production yield in mass, ranging from 6 to 12% at 279 K after 10 weeks. Several amino acids - alanine, glycine and aspartic acid - and perhaps the uracil nucleobase were also produced with yields from 0.001 to 0.4%. The determination of production yields carried out by the present study is a major step into the characterization of potential aerosols evolution on Titan.

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