The ν1 and ν3 bands of 18O3 and 18O16O18O: Line positions and intensities

Details The ν1 and ν3 bands of 18O3 and 18O16O18O: Line positions and intensities The ν1 and ν3 bands of 18O3 and 18O16O18O: Line positions and intensities

Mar 1987

adsabs.harvard.edu/cgi-bin/nph-data_query?bibcode=1987jmosp.122..221f&link_type=abstract

Journal of Molecular Spectroscopy, Volume 122, Issue 1, p. 221-228.

Computer Science

20

Scientific paper

Using 0.005 cm-1 resolution Fourier transform spectra of 18O-enriched ozone samples, an extensive analysis of the ν1 and ν3 bands of the two isotopic species 18O3 and 18O16O18O has been performed. The experimental rotational energy levels of the (100) and (001) vibrational states of both species were then reproduced with the aid of a Hamiltonian, taking explicitly into account the Coriolis interaction affecting the upper vibrational states. Accurate vibrational energies and rotational constants were derived and used together with an appropriate expansion of the transformed transition moment operators of the ν1 and ν3 bands to generate a complete and reliable list of line positions, intensities, and lower state energies for both isotopic species 18O3 and 18O16O18O.

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