The gamma system of zirconium oxide

Astronomy and Astrophysics – Astrophysics

Scientific paper

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Astronomical Spectroscopy, Line Spectra, Spectrum Analysis, Stellar Spectra, Zirconium Oxides, Molecular Spectroscopy, Zirconium Isotopes

Scientific paper

Fifteen bands of the gamma system of (Zr-90)O in the spectral region from 5916 to 7565 A are analyzed on the basis of laboratory spectrograms. The observed R heads of the bands are tabulated, along with the zero-rotation origins of the three subbands of each band, the observed triplet splittings, and the molecular constants for each band. Anomalous triplet splittings due to spin-orbit and spin-spin interactions are examined. Molecular constants are predicted for the oxides of the isotopes Zr-91, Zr-92, Zr-93, and Zr-94. Calculated and observed line locations are compared for the 2-2 band of (Zr-94)O.

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