The ``on the energy shell'' simplification of the impulse approximation in Rydberg atom-neutral collisions

Computer Science

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Multiphoton Ionization And Excitation To Highly Excited States, Intermolecular And Atom-Molecule Potentials And Forces, Line And Band Widths, Shapes, And Shifts

Scientific paper

Three types of calculations are compared according to the approximations used for the (e+B) scattering amplitude fe(q-->q'): (i) Exact impulse approximation (without any further approximation); (ii) Impulse approximation+``on the energy shell'' approximation; (iii) Impulse approximation+``on the energy shell'' approximation+``scattering length'' approximation. Preliminary results have been obtained for Na(n,l)+Ar collisions, suggesting that the ``on the energy shell'' approximation breaks down for large momentum transfers Q.

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