Mercury's core fraction and ancient crustal composition: Predictions from planetary formation under extremely reducing conditions

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5410 Composition (1060, 3672), 5430 Interiors (8147), 5455 Origin And Evolution, 5470 Surface Materials And Properties, 6235 Mercury

Scientific paper

Several hypotheses have been suggested to explain the paradox of Mercury's large core, which is on the order of sixty percent of the mass of the planet and recently demonstrated to be at least partially molten. Here we suggest that extremely reducing conditions in the earliest stages of planetary accretion nearest to the Sun may have produced the unusual metallic iron fraction by reducing iron otherwise bound into silicates. We demonstrate the formation conditions necessary for various meteoritic bulk compositions to produce the core/mantle ratio of Mercury. During this hypothetical core formation, we assume the remaining silicate fraction of Mercury (now largely lacking iron) has been heated to produce a magma ocean. The resulting cumulate mantle composition is calculated in a Matlab simulation of magma ocean solidification using a CMAS system adapted for Mercury. Plagioclase flotation, frequently cited as the necessary signature of a magma ocean, is highly dependent upon initial bulk composition. We demonstrate the initial silicate iron content of the magma ocean necessary to make plagioclase buoyant and thus produce a plagioclase flotation crust as seen on the Moon. In addition, over a range of bulk compositions the solidified mantle cumulates are unstable to gravitational overturn. During overturn hot cumulates rise from depth and may cross their solidi and melt, producing an earliest planetary crust. This crust may still exist on Mercury. With the first flyby results of the MESSENGER mission coming this winter, predictions from these models can be compared with initial ground measurements.

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