Distribution of Rb, Sr and Ni in igneous rocks, central and western Aleutian Islands, Alaska

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New analyses of Rb, Sr and Ni in 64 igneous rocks from the Aleutian Islands reveal the following geochemical characteristics: 1. (1) trends of increasing Rb content, Rb/Sr, and K/Sr and decreasing K/Rb in the sequence basalt-andesite-dacite; 2. (3) low Rb content and high K/Rb (always > 300); 3. (3) Sr content approximately equal in the three major rock types on the average; and 4. (4) generally low Ni content ( < 20 ppm in most of the basalts and all but one of the more siliceous rocks). These results, together with the known major-element chemistry of the rocks, indicate serious quantitative difficulties in the derivation of the Aleutian andesites from basalt magma by fractional crystallization or by contamination with sea-floor sediment. Calculations of the fractionation of K, Rb, Sr and Ni during partial melting of several ultramafic and mafic assemblages indicate the following: 1. (1) if andesite is derived directly from mantle peridotite by hydrous partial melting, the extent of melting must be small ( < 10 per cent). 2. (2) The average composition of six Aleutian basalts with tholeiitic affinities can be closely matched by about 30 per cent partial melting of a high-pressure, hydrous assemblage (garnet amphibolite) with the major- and trace-element chemistry of oceanic tholeiite. 3. (3) The K---Rb---Sr distribution observed in the entire spectrum of Aleutian rocks can be approximated by 1-30 per cent partial melting of altered oceanic tholeiite in a high pressure, anhydrous assemblage (garnet granulite). The exact means of deriving Ni-poor rocks from this assemblage is not clear, but several possibilities exist.

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