Nuclear Spin and Hyperfine Structure in Band Spectra.

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RECENTLY, S. Mrozowski1 has found that the band lines in the spectrum of mercury hydride (HgH) are split into several narrow components of constant or nearly constant separation (~0.02 A.). The bands investigated belong to a sequence ν' = 0, ν'' = 0, 1, 2, 3 in the transition . Apparently the approximate formula for the isotope effect in band spectra, , fails completely to explain this case, and so Mrozowski concludes that the separation may be interpreted as a hyperfine structure in a more restricted sense, that is, it is caused by the magnetic or electric constitution of the atomic nuclei.

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