Electrons in Nearly Periodic Fields

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Scientific paper

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Scientific paper

A detailed investigation is made of the change in the energy spectrum of a single electron in a pure metal brought about by the addition of small quantities of other elements in solid solution. To obtain numerical results the foreign atoms are represented by exponentially screened positive charges. The combined effects of line displacement and line broadening are determined and the change in the density of states at the Fermi limit is calculated. It is shown that the distortion of the energy band depends critically on the nature of the electronic states in the pure metal. Comparisons are made with the observed electronic specific heats of silver-based and copper-based solid solutions.

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