An experimental study of the partitioning of K, Rb, Cs, Sr and Ba between clinopyroxene and liquid at high pressures

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The partition coefficients of K, Rb, Cs, Sr and Ba between clinopyroxene and liquid were experimentally determined in the system diopside-albite-anorthite-water at 15-30 kb and 1100-1200°C. Clinopyroxene and liquid (glass) were separated by a new technique (differential dissolution technique--DDT) and analyzed by isotope dilution. The partition coefficients lie in the range 0.054-0.081 for Sr, 0.0014-0.0026 for K, 0.00078-0.0023 for Ba, 0.0010-0.0041 for Rb, 0.00035-0.0036 for Cs. Variations of the partition coefficients with pressure, temperature and composition of the phases are relatively small, though no systematic study of these parameters was attempted.

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