Annealed HAC mantles in diffuse dust clouds

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Carbon, Cosmic Dust, Interstellar Matter, Molecular Clouds, Silicates, Absorption Spectra, Amorphous Materials, Hydrogenation, Infrared Spectra, Optical Thickness

Scientific paper

Carbon grains in the diffuse cloud medium consist of HAC mantles accreted on to silicate-oxide cores. It is shown that laboratory data support a model in which the ratio of sp3 to sp2 hybridized carbon atoms is a function of the mantle temperature and varies from one interstellar cloud to another. Cold mantles are characterized by a high proportion of sp3 diamond-like carbon and a 3.4-micron absorption band in the spectrum of highly reddened field stars. It is shown that the HAC model agrees with observations of the 3.4-micron absorption feature, provided that cold mantles have no more than 30 percent of the carbon atoms chemisorbed to hydrogen. In diffuse interstellar clouds showing low dust obscuration, mantle heating by ultraviolet starlight shifts the bonding structure from diamond-like (sp3) to graphitic (sp2) carbon. The hot HAC mantles would then show a ubiquitous 3.3-micron emission feature in the diffuse cloud medium and no 3.4-micron feature at all. Thus, variations of the sp3/sp2 ratio with mantle temperature can explain why the 3.4-micron band frequently appears in absorption, whereas the 3.3-micron band always appears in emission.

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