Hydrogen and helium broadening and pressure induced line shifts of 13CH4 in the ν4 band.

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Line Broadening: Methane

Scientific paper

Hydrogen and helium pressure induced broadening and line shifts of the ν4 band of isotopic methane (13CH4) have been measured at room temperature for many lines in the P, Q and R branches. The measurements were obtained using the 1 m Fourier Transform Spectrometer at the KPNO McMath Solar Telescope with a spectral resolution of 0.0065 cm-1. Data were obtained for 266 absorption lines for a range of J values up to J = 16; the pressure broadening results are compared to similar measurements made for the common isotope 12CH4 and a small, but consistent variation is noted.

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