An update of and suggested increase in calculated radiative association rate coefficients

Details An update of and suggested increase in calculated radiative association rate coefficients An update of and suggested increase in calculated radiative association rate coefficients

Apr 1985

adsabs.harvard.edu/cgi-bin/nph-data_query?bibcode=1985apj...291..226h&link_type=abstract

Astrophysical Journal, Part 1 (ISSN 0004-637X), vol. 291, April 1, 1985, p. 226-229.

Statistics

Computation

62

Association Reactions, Computational Astrophysics, Interstellar Chemistry, Molecular Clouds, Reaction Kinetics, Methyl Alcohol, Molecular Ions, Spontaneous Emission, Temperature Dependence

Scientific paper

The theoretical evidence that recently calculated radiative association reaction rate coefficients involving polyatomic molecular ions may be an order of magnitude too low in many cases is explained and developed. A faster radiative stabilization rate is utilized to lessen the discrepancy between theory and experiment on the important interstellar association between CH3(+) and H2. Proposed update rate coefficients for a variety of radiative association processes in the 10-50 K temperature range are given for inclusion in future models of dense interstellar clouds.

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