Competing sources of heavy CO2 enhancement in the stratosphere and magnitude of heavy O3 enhancement

Details Competing sources of heavy CO2 enhancement in the stratosphere and magnitude of heavy O3 enhancement Competing sources of heavy CO2 enhancement in the stratosphere and magnitude of heavy O3 enhancement

Jun 1991

adsabs.harvard.edu/cgi-bin/nph-data_query?bibcode=1991p%26ss...39..945b&link_type=abstract

Planetary and Space Science (ISSN 0032-0633), vol. 39, June 1991, p. 945-950.

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1

Atmospheric Composition, Carbon Dioxide Concentration, Isotopic Enrichment, Oxygen Isotopes, Ozone, Stratosphere, Abundance, Atmospheric Chemistry, Oxygen 17, Oxygen 18

Scientific paper

The effect of the avoided crossing of the O3 (1 1B2) state, which is reached by absorption in the Hartley band, is noted to be an alternative source for the heavy CO2 enhancement in the stratosphere that is commonly believed to be a consequence of heavy O3 enhancement. It is suggested that the two sources could be of equal importance, if the heavy O3 enhancement is of the order of 22.5 percent. It is not apparent that there could be another path to isotopic fractionation through termolecular association, if the O3 distribution among its internal modes is statistical.

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