Population anti-inversion in the 2(0) - 3(-1)E transition of CH3OH

Astronomy and Astrophysics – Astronomy

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Electron Transitions, Interstellar Matter, Methyl Alcohol, Molecular Absorption, Molecular Clouds, Interstellar Masers, Molecular Collisions, Molecular Excitation, Molecular Rotation, Radiative Transfer

Scientific paper

To investigate the observed absorption of the 2(0) - 3(-1)E transition of CH3OH at 12.2 GHz against the 2.7-K microwave background, statistical equilibrium calculations involving radiative transitions, collisional transitions, and photon trapping have been carried out for the lowest 69 rotational levels of E-species CH3OH. The results show that population anti-inversion of the transition is a combined effect of spontaneous transitions and non-dominating collisional excitation. For molecular clouds not associated with continuum emission, stronger absorption at the transition is expected from warmer clouds. An E-species CH3OH abundance of 10 exp -8 - 10 exp -9 is derived. The model also suggests that the transition can occur as a maser emission in the presence of a bright continuum background with a temperature higher than the kinetic temperature of the cloud. The results are used to re-assess the CH3OH properties of the giant molecular cloud G 1.6-0.025.

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