Theoretical reinvestigation of hydrocarbon and cyanoacetylene abundances in TMC-1

Astronomy and Astrophysics – Astrophysics

Scientific paper

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Abundance, Hydrocarbons, Interstellar Chemistry, Molecular Clouds, Nebulae, Acetylene, Cyano Compounds

Scientific paper

The products of the reaction between C3H+ and H2 at low temperatures were previously reported incorrectly by the authors to be C3H2+ + H. The only product at 80K (and presumably at lower temperatures) is C3H3+, formed via a saturated three-body association reaction. Use of the analogous radiative association reaction with a rate coefficient of 10-11cm3s-1 as well as a newly measured rate coefficient for the radiative association reaction between CH3+ and H2 in Herbst's "semidetailed" model of the dense interstellar cloud TMC-1 results in improved agreement between theoretical and observed hydrocarbon and cyanoacetylene abundances.

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