The computation of band strengths of diatomic molecules. II - Vibrational transitions

Statistics – Computation

Scientific paper

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Diatomic Molecules, Dipole Moments, Franck-Condon Principle, Morse Potential, Oscillator Strengths, Vibrational Spectra, Computational Astrophysics, Computational Chemistry, Electron Transitions, Ground State, Late Stars, Molecular Energy Levels, Stellar Atmospheres

Scientific paper

A recursive analytic method based on the Morse potential function that was adopted for numerical computation of Franck-Condon factors and related quantities in a previous paper, Sharp (1984), is modified for the calculation of vibrational band strengths within the same electronic state. Although this method is not intended to replace more accurate numerical integration, it is presented as an alternative method of efficiently computing many band strengths that can be used for computing molecular absorption in stellar atmospheres if high accuracy is not required, or accurate spectroscopic constants are not available, but is considerably better than calculations based on very simple harmonic oscillators.

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