Para-Localization Energy (Free-Electron Molecular-Orbital Method) and Polarographic Half-Wave Potentials of some Polynuclear Hydrocarbons

Details Para-Localization Energy (Free-Electron Molecular-Orbital Method) and Polarographic Half-Wave Potentials of some Polynuclear Hydrocarbons Para-Localization Energy (Free-Electron Molecular-Orbital Method) and Polarographic Half-Wave Potentials of some Polynuclear Hydrocarbons

Apr 1957

adsabs.harvard.edu/cgi-bin/nph-data_query?bibcode=1957natur.179..829f&link_type=abstract

Nature, Volume 179, Issue 4564, pp. 829 (1957).

Computer Science

4

Scientific paper

POLYNUCLEAR aromatic hydrocarbons in 75 per cent dioxane solution which contains 0.175 M tetrabutyl ammonium iodide are reducible in the dropping mercury electrode1. As shown by the corresponding polarograms, it is a two-electron addition step process, and it is similar to the reduction of these compounds by alkali metals or their amalgams and alcohol2, a fact which can be easily explained.

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