Band-model parameters for 4.3 micron CO2 band in the 300-1000 K temperature region

Computer Science

Scientific paper

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Absorption Spectra, Carbon Dioxide, Gas Spectroscopy, Infrared Spectra, Spectral Bands, Transmittance, Absorptivity, Fourier Transformation, Graphs (Charts), Tables (Data), Temperature Effects

Scientific paper

Moderate resolution (0.06/cm) Fourier-transform transmission spectra of the 4.3 micron band of CO2 were acquired at selected pressures and concentrations over a temperature range from 300 to 1000 K. These spectra were degraded to a 5/cm bandpass and fit to a combined Lorentz-Doppler-broadening band model to determine band-model parameters utilizing a nonlinear least-square algorithm. Comparisons of selected band-model parameters are made with preexisting data. Spectrally degraded line-by-line spectral calculations are compared with spectra calculated using the band-model parameters determined in this work.

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