Carbon and oxygen isotope variations in precambrian cherts

Mathematics – Logic

Scientific paper

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Scientific paper

Isotopic compositions of O in bulk Precambrian cherts and of C in the insoluble organic matter trapped in the silica have been determined. A general negative correlation relates these two variables and indicates that postdepositional alteration may have markedly modified the pristine isotopic ratios of the C compounds and their hosts. This interpretation is in good agreement with the expected isotopic trends for C and O resulting from secondary geological thermal events. Based on this correlation, a maximum 13 C value of ca . - 33%./ PDB is proposed for the Precambrian kerogen. The difference between Proterozoic and Phanerozoic (-27%.) 13 C values could be linked to the flowering of life at the end of the Precambrian.

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