Relativistic Configuration and Many-body purterbation Calculations of 3-> 2 Transition Wavelengths of L-shell ions

Astronomy and Astrophysics – Astrophysics

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A combined relativistic configuration interaction and second order many-body purterbation theory is applied to calculate the wavelengths of 3-> 2 transitions of L-shell Fe and Ni ions. A comparison of calculated n=2 level energies with experimental results indicates that these levels are accurate to within ˜± 0.1 eV. The calculated 3->2 transition wavelengths of L-shell Fe ions are compared with the expiremental measurements from Lawrence Livermore electron beam ion traps. It is found that the second order many-body purterbation corrections improve the wavelengths significantly over the standard relativistic configuration interaction calculations. A complete table of 3-> 2 line list is presented for L-shell ions of Fe and Ni, with estimated wavelength uncertainties of < 10 m{Å}. Such a table is expected to be useful in X-ray spectral analysis of a wide variety of astrophysical sources.

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