Molecular Spectroscopy with the Biggest Night-Sky Spectrograph in the World

Astronomy and Astrophysics – Astronomy

Scientific paper

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Scientific paper

The emission lines of the night sky, recorded on every astronomical spectrogram, are in many ways a nuisance to observers, but they also provide a highly accurate standard wavelength reference system. There are OH Meinel main-band lines with wavelengths known to 0.00001 Angstroms in every echelle order from lambda5800 to lambda10600 . the present practical CCD limit. In addition, using coadded spectra from many observers taken with HIRES on the Keck I telescope, we have constructed a night-sky spectrum averaging 100 hours exposure from lambda5770 to lambda7075 , decreasing gradually to 30 hours at lambda8000 . On it and similar, earlier, shorter-exposure summed spectra many satellite lines of OH have been identified, also many isotopic main-band lines of (18) OH, and also four main-band lines from the previously unobserved (in the night sky) level v' = 10. Also, many previously unobserved O_2 atmospheric bands have been detected and identified, to higher vibrational energy levels than measured in the laboratory, and the complicated interplay of absorption and emission in the (16) O(16) O (with alternate rotational levels nonexistent), (16) O(17) O and (16) O(18) O bands have been studied.

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