Astronomy and Astrophysics – Astronomy
Scientific paper
Jul 1995
adsabs.harvard.edu/cgi-bin/nph-data_query?bibcode=1995apj...448..232c&link_type=abstract
Astrophysical Journal v.448, p.232
Astronomy and Astrophysics
Astronomy
99
Ism: Abundances, Ism: Clouds, Ism: Molecules, Molecular Processes
Scientific paper
We have investigated the gas-phase chemistry in dense cores where ice mantles containing ethanol and other alcohols have been evaporated. Model calculations show that methanol, ethanol, propanol, and butanol drive a chemistry leading to the formation of several large ethers and esters. Of these molecules, methyl ethyl ether (CH3OC2H5) and diethyl ether [(C2H5)2O] attain the highest abundances and should be present in detectable quantities within cores rich in ethanol and methanol. Gas-phase reactions act to destroy evaporated ethanol and a low observed abundance of gas-phase C2H5OH does not rule out a high solid-phase abundance. Grain surface formation mechanisms and other possible gas-phase reactions driven by alcohols are discussed, as are observing strategies for the detection of these large interstellar molecules.
Charnley Steven B.
Kress Monika E.
Millar Thomas J.
Tielens Alexander G. G. M.
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